期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 67, 期 3, 页码 355-363出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2009.04.001
关键词
Photocatalysis; TiO2; Congo Red; Kaolinite; Annular reactor; Degradation
资金
- Australian Research Council Linkage [LP0562153]
- Australian Water Quality Centre through the Water Environmental Biotechnology Laboratory (WEBL) at the University of Adelaide
In this study, an annular photocatalytic reactor (APR) system was designed and operated to optimise the photocatalytic degradation of Congo Red (CR) using a newly synthesized titania impregnated kaolinite photocatalyst (TiO2/K). The design parameters of the APR: reactor configuration, mass transfer, mixing and hydrodynamics were discussed. The influences of the operation parameters: pH, critical TiO2/K loading, aeration rate and initial CR concentration on the photocatalytic performances were studied in a batch operation mode. Results showed that the initial pH was the most crucial operation parameter that significantly affected both the adsorption and photocatalytic reactions in the APR-TiO2/K system. The point of zero charge for TiO2/K was found to shift towards pH 9.5. The complete degradation of 40 ppm CR was attained in 4 h. Possible intermediates and by-products during the CR degradation were identified using the LC/MS technique. The TiO2/K reactivation study showed that the TiO2/K particles are highly stable and have a modest improvement in photoactivity for every recycle trial up to at least five cycles. The overall results revealed that the APR-TiO2/K system has promising application for the development of a technically feasible and cost-effective industrial water and wastewater treatment process. (C) 2009 Elsevier B.V. All rights reserved.
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