期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 276, 期 -, 页码 304-312出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2018.08.092
关键词
Bisphenol A; Electrochemical sensor; Ultrasound assisted magnetic molecularly imprinted polymer; Gold nanoparticles; Carbon black nanoparticles
资金
- European project Sensing toxicants in Marine waters makes Sense using biosensors (SMS) Grant [613844]
Sample preparation is considered as one of the most interesting applications of magnetic molecularly imprinted polymer (MagMIP) used as adsorbents for various compounds prior to their determination using the developed analytical techniques. In this context, we present in this paper a developed Ultrasound-assisted magnetic molecularly imprinted polymer (US-MagMIP) combined to an electrochemical sensor modified with a nanocomposite of carbon black nanoparticles (CBNPs), and Gold nanoparticles (AuNPs) for highly selective and sensitive detection of Bisphenol A (BPA). The electrochemical characterization of the developed sensor was investigated by electrochemical impedance spectroscopy and cyclic voltammetry. Various parameters were optimized such as the effect of voltammetric mode, the effect of pH, the amount of US-MagMIP and the rebinding time. The electrochemical sensor exhibits a high sensitivity for BPA with a LOD of 8.8 nM with a wide linear range from 0.07 mu M to 10 mu M. Moreover, this sensor provides a high selectivity towards various likely interferents by combination with US-MagMIP prior to analysis. The developed analytical approach was applied successfully for determination of BPA in Tap and mineral water samples.
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