期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 176, 期 -, 页码 850-857出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2012.09.049
关键词
Triarylborane; Ratiometric sensor; Fluoride; Fluorescence; Phenanthroimidazole
资金
- Basic Science Research Program [2010-0008264, 2007-0056341, 2012039773]
- Priority Research Centers Program through the National Research Foundation of Korea (NRF) [2009-0093818]
- Ministry of Education, Science and Technology
- KISTI [KSC-2011-C2-18]
Triarylborane-phenanthroimidazole conjugates 1 and 2 linked by a biphenylene and phenylene group, respectively, were prepared and characterized. Both compounds are highly fluorescent ( Phi = 0.49-0.74 for 1 and Phi = 0.71-0.92 for 2) and show a positive solvatochromism. Upon fluoride binding to the boron center, they exhibit a ratiometric fluorescence response (Delta lambda(em) = 84 nm for 1 and 63 nm for 2 in acetone) accompanying a vivid emission color change. Photophysical data and TD-DFT studies suggest that intramolecular charge transfer (ICT) transition from a phenanthroimidazole donor to a borane acceptor in the neutral 1 is switched to pi-pi* transition of phenanthroimidazole moiety after fluoride binding. Due to the greater elevation of LUMO level by fluoride complexation, the resulting fluoride adduct [ 1F]fluoresces at the apparently blue-shifted region. (C) 2012 Elsevier B.V. All rights reserved.
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