期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 178, 期 -, 页码 125-131出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2012.12.070
关键词
Cupric oxide nanoparticles; Mesoporous carbons; Non-enzymatic; Sensor; Glucose
资金
- National Science Foundation of China [21105006, 21175016]
- Natural Science Foundation of Jiangsu [BK2011239]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
A convenient method was developed to directly attaching cupric oxide nanoparticles (CuONPs) on mesoporous carbons (MCs) for sensitive amperometric non-enzymatic sensing of glucose. The CuONPs-MCs nanocomposite was characterized with transmission electron microscopy and X-ray diffraction. Based on the advantageous functions of CuONPs and MCs, the functional nanocomposite modified glassy carbon electrode showed high electrocatalytic activity toward the oxidation of glucose. Due to the electrocatalytic activity to glucose, a non-enzymatic glucose sensor was constructed based on the CuONPs-MCs nanocomposite. Under optimal experimental conditions, the designed sensor exhibited a wide linear response to glucose ranging from 4 x 10-(7) to 7.3 x 10(-3) M with a high sensitivity of 1154.1 mu A mM-(1) cm-(2) and a low detection limit down to 0.1 mu M at the signal to noise ratio of 3. This sensor showed good accuracy, acceptable precision and reproducibility. The assay results of glucose in human blood serums with the proposed method were in a good agreement with the reference values. The functionalization of MCs with CuONPs provided good biocompatible platform for sensing and catalysis. (c) 2013 Elsevier B.V. All rights reserved.
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