期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 164, 期 1, 页码 69-75出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2012.01.071
关键词
Thiacalix[4]arene derivative; Multifunction chemosensor; Ag+; AcO-
资金
- Natural Science Foundation of China [21165006]
- Fund of the International cooperation projects of Guizhou Province [20107002]
- Chinese Ministry of Education [Z 2009-1-52001]
The synthesis and spectroscopic studies of a thiacalix[4]arene-based sensor of 1,3-alternate-25,27-bis(2-aminoethoxy)-26,28-bis(2-methoxyethyl)-thiacalix[4]arene linked 4-chloro-7-nitrobenzofurazan (NBD-Cl) are described. The properties of the compound were evaluated and show that it is a colorimetric and fluorescence sensor for Ag+ and AcO-. The addition of Ag+ results in a red shift of the absorption spectrum of the sensor, which is clearly visible to the naked eye, accompanied by a strong quenching of the fluorescence. With the addition of AcO-. the fluorescence was severely quenched, and the absorbance increased significantly, with a new absorption band appearing at shorter wavelength. This demonstrated that the multifunctional sensing compound prepared from a novel thiacalix[4]arene was highly selective for AcO-. (C) 2012 Elsevier B.V. All rights reserved.
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