Nanocrystalline graphite-like pyrolytic carbon film electrode for electrochemical sensing of hydrazine

Pyrolytic carbon film (PCF) electrode fabricated by a non-catalytic chemical vapor deposition (CVD) process was used as an electrochemical sensor for the detection of hydrazine. The electrode response was found to be electrocatalytic producing a reduction in the overpotential compared to other unmodified carbon-based electrodes such as glassy carbon (GC), basal-plane pyrolytic graphite (BPPG), and edge-plane pyrolytic graphite (EPPG) electrodes. The overall number of electrons involved in the electrooxidation of hydrazine, the number of electrons involved in the rate-determining step, and diffusion coefficient of hydrazine at PCF electrode were estimated using cyclic voltammetry and chronoamperometry. The performance of PCF electrode was comparable to and in some cases even better than many chemically modified electrodes in terms of detection limit, linear dynamic range, and sensitivity. Moreover, the sensor exhibited fast response time (within 2s), high response stability, and reproducibility. All the results indicated this sensor is suitable for hydrazine analysis. (C) 2011 Elsevier B.V. All rights reserved.