期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 155, 期 2, 页码 909-914出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2011.01.041
关键词
Colorimetric anion sensor; Phosphate; Pyrophosphate anions; Per-6-ammonium-beta-cyclodextrin; p-Nitrophenol; Aqueous medium
资金
- University Grants Commission (UGC), New Delhi, INDIA [10-2(5)/2007(i)-E.U.II]
Using per-6-ammonium-beta-cyclodextrin (per-6-NH(3)(+)-beta-CD) as an anion binding site and p-nitrophenol as a spectroscopic probe, a colorimetric sensor is developed for phosphate and pyrophosphate anions in water. Per-6-NH(3)(+)-beta-CD forms a 1:2 inclusion complex with p-nitrophenol as characterized by NOESY and ESI-MS spectra and it undergoes a distinct color change from colorless to intense yellow upon exposure to phosphate or pyrophosphate anions over other anions including perchlorate, ATP(2-), ADP(2-) and AMP(2-). The seven ammonium groups of 1, bind phosphate (characterized by ESI-MS) or pyrophosphate anions specifically by electrostatic interaction. This naked eye sensing is significant for very low concentration (5 x 10(-5) M) of anion with 1:2 ratio of host and guest. (C) 2011 Elsevier B.V. All rights reserved.
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