Potentiometric VOC detection in air using 8YSZ-based oxygen sensor modified with SmFeO3 catalytic layer

Potentiometric oxygen sensor was fabricated and applied to detect several volatile organic compounds (VOCs; acetic acid, methylethylketone (MEK), ethanol, benzene, toluene, o- and p-xylene) at sub-ppm levels in the temperatures range of 400-500 degrees C. The electromotive force (EMF) linearly changed with the logarithm of VOC concentration. Especially for ethanol and MEK, the sensitivity and EMF at 1 ppm were distinctly lowered for the sensor with the SmFeO3 coated Pt working electrode. It seems that ethanol and MEK were more easily oxidized on the SmFeO3 surface than the other VOCs. A discriminative detection of ethanol and MEK apart from the others could be achieved with the combination of two types of the sensors, Pt|8YSZ|Pt(ref.) and SmFeO3/Pt|8YSZ|Pt(ref.). (c) 2009 Elsevier B.V. All rights reserved.