Fabrication and characterization of carbon nanotube array electrodes with gold nanoparticle tips

In this work we fabricated 8 mm long aligned multi-walled carbon nanotube array electrodes and electrochemically deposited gold nanoparticles in a controlled manner onto the nanotube tips at the top of the array. A soldering technique was also developed to provide reliable electrical contact between the carbon nanotubes at the bottom of the array and copper on a patterned printed circuit board. The top surfaces of the nanotube tower electrodes were activated using a reactive ion etcher prior to gold deposition. Electrodeposition of Au particles on the plasma-treated tower electrodes was performed over a range of deposition times and potentials. Cyclic voltammetry and electrochemical impedance spectroscopy analyses showed that the Au-deposited carbon nanotube array electrodes were successfully fabricated. The new electrodes will be the foundation for further biosensor development using self-assembled monolayers and bio-conjugation of antibodies for novel label-free immunosensing. (c) 2008 Elsevier B.V. All rights reserved.