Single quantum dot-micelles coated with gemini surfactant for selective recognition of a cation and an anion in aqueous solutions

The synthesis of quantum dot coated with cetyltrimethyl ammonium bromide (CTAB) and gemini surfactant [C12H25N+(CH3)(2)(CH2)(4)(CH3)(2)N+C12H25]center dot 2Br(-) (C12-4-12) in aqueous solution have been described. It is characterized by photoluminescent spectroscopy, UV-vis spectroscopy and transmission electron microscopy (TEM), etc. In comparison with CTAB-coated QDs, the QDs coated with C12-4-12 respond selectively to both transition metal ion copper and fluoride ion in aqueous media. When Cu2+ is bound to C12-4-12-coated QD micelles, the fluorescence intensity is quenched. Linear relationships are found between the relative fluorescence intensity and the concentration of Cu2+ in the range 0-500 mu M, which is best described by a Stern-Volmer-type equation. Meanwhile, it is found that F- enhanced the luminescence of the C12-4-12-coated QD micelles in a concentration dependence that is described by a Langmuir binding isotherm equation in the range 0-300 mu M. The limits of detection of Cu2+ and F- are 1.1 and 0.68 mu M, respectively. The possible mechanism is discussed. (C) 2008 Elsevier B.V. All rights reserved.