Particle deposition fluxes of BDE-209, PAHs, DDTs and chlordane in the Pearl River Delta, South China

Year-round bulk air deposition samples were collected at 15 sites in the Pearl River Delta (PRD) on a bimonthly basis from Dec 2003 to Nov 2004, and the particle-phase deposition of BDE-209, PAHs, DDTs and chlordane was measured. The annual deposition fluxes of BDE-209, total PAHs (15 compounds), total DDT (sum of p,p'-DDE, p,p'-DDD, p,p'-DDT, and o,p'-DDT), and chlordane (sum of trans-chlordane and cischlordane) varied from 32.6 to 1970 mu g m(-2)yr(-1), 22 to 290 mu g m(-2)yr(-1), 0.8 to 11 mu g m(-2)yr(-1), and 0.25 to 1.9 mu g m(-2)yr(-1), respectively. Spatial variations were higher in the centre of the PRD and lower at the coastal sites for all compounds. The seasonal variations of deposition were found to be compound-dependent, influenced by a number of factors, such as the timing of source input, temperature, and precipitation etc. In particular, source input time affected the deposition fluxes of BDE-209 and high-weight PAHs, while temperature-dependent gas-particle partitioning was a key factor for DDT and light-weight PAH deposition. During the whole sampling period, the atmospheric deposition of BDE-209, Sigma PAHs, Sigma DDTs, and chlordane onto Hong Kong reached about 93, 86, 2.1 and 2.1 kg yr(-1), respectively, and onto the PRD reached about 13.400, 2950, 82, and 63 kg yr(-1). By comparing the calculated total air deposition with the burden in the soils, the half residual time of BDE-209 in soils was estimated to be 3 years. (C) 2010 Elsevier B.V. All rights reserved.