期刊
SCIENCE OF THE TOTAL ENVIRONMENT
卷 408, 期 16, 页码 3464-3468出版社
ELSEVIER
DOI: 10.1016/j.scitotenv.2010.04.032
关键词
2,4-dinitrotoluene; Persulfate; Sulfate radical; Zero-valent iron
资金
- University of Ulsan South Korea [2009-0139]
- National Research Foundation of Korea [핵C6B1609] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The oxidation of 2,4-dinitrotoluene (DNT) by persulfate (S2O82-) activated with zero-valent iron (Fe-o) was studied through a series of batch experiments. The mechanism for Fe-o activation was investigated by comparing with Fe2+, and the effects of persulfate-to-iron ratio and pre-reduction on DNT oxidation were examined. DNT was stable in the presence of persulfate and transformed only when Fe-o was added. Most DNT was degraded oxidatively by Fe-o-activated persulfate, whereas direct reduction of DNT by Fe-o was unimportant. The rate of DNT degradation increased with higher Fe-o dose, presumably due to increasing activation of persulfate by Fe-o and Fe2+. In contrast to the Fe-o-persulfate system, where complete oxidation DNT was achieved, only <= 20% of DNT was degraded and the reaction was terminated rapidly when Fe-o was replaced with equimolar Fe2+. This indicates that Fe-o is more effective than Fe2+ as activating agent and potentially more suitable for environmental applications. The reduction products of DNT were more rapidly oxidized by persulfate than DNT, suggesting that converting the nitro groups of NACs to amino groups prior to oxidation can greatly enhance their oxidation. This suggests that a sequential Fe-o reduction-persulfate oxidation process may be an effective strategy to promote NAC degradation. (C) 2010 Elsevier B.V. All rights reserved.
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