期刊
RSC ADVANCES
卷 5, 期 102, 页码 84038-84043出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra14979g
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资金
- Chongqing Key Laboratory for Advanced Materials and Technologies of Clean Energies [cstc2011pt-sy90001]
- Southwest University and Chongqing Science and Technology Commission [SWU111071, cstc2012gjhz90002]
- Fundamental Research Funds for the Central Universities [SWU 113079, XDJK2014C051]
A mesoporous carbon matrix derived from MOF-Ni prepared via a hydrothermal method was used for encapsulating selenium as a cathode material for Li-Se batteries. Thermogravimetric analysis and energy-dispersive X-ray analysis confirm that selenium is highly homogeneously distributed in the composite with a mass loading up to 48%. It exhibits an initial discharge capacity of 599.7 mA h g(-1) and retains 417 mA h g(-1) with a high coulombic efficiency of 99.9% after 100 cycles at a high rate of 3C, of which the excellent electrochemical performance is mainly attributed to the high conductivity and the hollow structure of the carbon matrix.
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