期刊
SCIENCE CHINA-CHEMISTRY
卷 55, 期 7, 页码 1213-1219出版社
SCIENCE PRESS
DOI: 10.1007/s11426-012-4492-2
关键词
water octamer; hybrid carboxylate-water decamer; dehydration-rehydration; helical chains
资金
- National Natural Science Foundation of China [50971063, 21053001]
- Natural Science Foundation of Fujian Province [2011J01047, 2003F006, 2010J01042]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry of China
- Huaqiao University [10BS210, 11BS102]
An octameric water moiety which consists of a chairlike water hexamer and two pendent water molecules in the 1,4-diaxial positions and shows a similar structure to the hydrocarbon (1r,4r)-1,4-dimethylcyclohexane, is unambiguously trapped in a 2D Cu(II) mixed-ligand coordination polymer, {[Cu-2(bpp)(2)(H2O)(2)(bpda)(2)]center dot 6H(2)O} (n) (1) (bpp = 1,3-bis(4-pyridyl)propane and H(2)bpda = 2,2'-biphenyldicarboxylic acid). The water octamer can be extended into a hybrid carboxylate-water decamer when carboxylic oxygen atoms from bpda(2-) are involved. Interestingly, the present hybrid decamer bears a similar structural topology to a butterfly (H2O)(10) cluster. The reversible dehydration/hydration of 1 is determined by X-ray powder diffraction studies.
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