期刊
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
卷 12, 期 3, 页码 -出版社
TAYLOR & FRANCIS LTD
DOI: 10.1088/1468-6996/12/3/034404
关键词
phosphor; green-emitting; white LEDs; oxynitride; beta-sialon
资金
- KAKENHI [208551]
- Program for New Century Excellent Talents in University [NCET-25-0290]
- National Natural Science Foundation of China [50672014, 50972025]
- Changjiang Scholars and Innovative Research Team in University [IRT0713]
- Grants-in-Aid for Scientific Research [23560811] Funding Source: KAKEN
We have synthesized Yb2+-activated Si(6-z)AlzOzN(8-)z (0.05 <= z <= 2.3, 0.03 mol% <= Yb2+ <= 0.7 mol%) green phosphors by solid-state reaction at 1900 degrees C for 2 h under a nitrogen pressure of 1.0 MPa. Phase purity, photoluminescence and its thermal quenching were investigated. A single phase was obtained for all values of z and Yb2+ concentration. A distinct emission band was observed at 540 nm originating from the 5d-4f electronic transition in Yb2+ under 480 nm excitation. The photoluminescence properties mainly depended on the Yb2+ concentration and chemical composition of the matrix. The resultant phosphor showed high thermal stability, that is, the emission intensity at 150 degrees C was about 82% of that measured at room temperature. The experimental results indicate that beta-SiAlON : Yb2+ is a potential green phosphor for white light-emitting diodes (LEDs), which use blue LEDs as the primary light source.
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