期刊
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
卷 9, 期 1, 页码 -出版社
TAYLOR & FRANCIS LTD
DOI: 10.1088/1468-6996/9/1/014103
关键词
metallo-supramolecular chemistry; metal ion coordination; polymers; polyelectrolyte amphiphile complex; polyoxometalate; surfactant-encapsulated cluster; mesophase; nanostructure; nanotechnology
Metal ion coordination in discrete or extended metallo-supramolecular assemblies offers ample opportunity to fabricate and study devices and materials that are equally important for fundamental research and new technologies. Metal ions embedded in a specific ligand field offer diverse thermodynamic, kinetic, chemical, physical and structural properties that make these systems promising candidates for active components in functional materials. A key challenge is to improve and develop methodologies for placing these active modules in suitable device architectures, such as thin films or mesophases. This review highlights recent developments in extended, polymeric metallo-supramolecular systems and discrete polyoxometalates with an emphasis on materials science.
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