4.6 Article

Naked-eye-based selective detection of pyrophosphate with a Zn2+ complex in aqueous solution and electrospun nanofibers

期刊

RSC ADVANCES
卷 5, 期 32, 页码 25229-25235

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra16742b

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资金

  1. National Natural Science Foundation of China [50903075, J1210060]
  2. New Teachers' Joint Fund for Doctor Stations from Ministry of Education of the People's Republic of China [20114101120003]
  3. Zhengzhou University

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A mononuclear zinc complex is shown to act as a highly selective naked-eye-based chemosensor for pyrophosphate (PPi) in aqueous solution. Based on the keto-enol transformation process, addition of PPi made the color of the sensor complex change from red to colorless. Moreover, electrospun nanofibers from the mononuclear zinc complex could detect PPi on site and in real-time and the color of the nanofibers changes rapidly after they were immersed in an aqueous solution of pyrophosphate.

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