期刊
RSC ADVANCES
卷 5, 期 11, 页码 8216-8222出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra09765c
关键词
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资金
- National High Technology Research and Development Program of China [2011AA050520]
- National Basic Research Program of China (973 Program) [2012CB932402]
- National Natural Science Foundation of China [51172203]
- Natural Science Funds for Distinguished Young Scholar of Zhejiang Province [R4110189]
- Public Welfare Project of Zhejiang Province [2013C31057]
- Swedish Energy Agency (Energimyndigheten)
- Swedish Research Council (VR)
A promising fabrication method of electron transporting interlayers for solution-processed optoelectronic devices by electrophoretic deposition (EPD) of colloidal zinc oxide (ZnO) nanocrystals was demonstrated. A low voltage of 3-5 V and a short deposition time of 40 s at room temperature were found to be sufficient to generate dense and uniform ZnO thin films. The EPD ZnO nanocrystal films were applied as ETLs for inverted organic solar cell and polymer light emitting diodes (PLEDs). By optimizing the EPD processing of ZnO nanocrystal electron transporting layers (ETLs), inverted organic solar cells based on [3,4-b]-thiophene/benzodithiophene (PTB7): [6-6]-phenyl-C71-butyric acid methyl ester (PC71BM) and poly(3-hexylthiophene) (P3HT): [6-6]-phenyl-C-61-butyric acid methyl ester (PC61BM) with an average PCE of 8.4% and 4.0% were fabricated. In combination with the PLEDs and flexible devices results, we conclude that the EPD processed ZnOnanocrystal thin films can serve as high quality ETLs for solution-processed optoelectronic devices.
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