期刊
RSC ADVANCES
卷 5, 期 18, 页码 13702-13708出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra16062b
关键词
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资金
- National Natural Science Foundation of China [21403022]
- Program for Liaoning Excellent Talents in University [LJQ2013059]
The asymmetric hydrogenation of N-arylimines with the chiral phosphine-phosphoramidite ligand, (S-c, S-a)-PEAPhos 2b, has been developed. The results revealed that the presence of the substituents on the 3,3'-positions of the binaphthyl backbone significantly improved the enantioselectivity. The utility of this methodology was demonstrated in the synthesis of the chiral fungicide (R)-metalaxyl.
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