期刊
SCIENCE
卷 323, 期 5921, 页码 1585-1590出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1169163
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资金
- UK Engineering and Physical Sciences Research Council [EP/C511794, GR/S77820]
- Engineering and Physical Sciences Research Council [EP/C511794/1] Funding Source: researchfish
The body-centered cubic A15-structured cesium fulleride Cs3C60 is not superconducting at ambient pressure and is free from disorder, unlike the well-studied face-centered cubic A(3)C(60) alkali metal fulleride superconductors. We found that in Cs3C60, where the molecular valences are precisely assigned, the superconducting state at 38 kelvin emerges directly from a localized electron antiferromagnetic insulating state with the application of pressure. This transition maintains the threefold degeneracy of the active orbitals in both competing electronic states; it is thus a purely electronic transition to a superconducting state, with a dependence of the transition temperature on pressure-induced changes of anion packing density that is not explicable by Bardeen-Cooper-Schrieffer (BCS) theory.
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