期刊
RSC ADVANCES
卷 5, 期 120, 页码 98757-98761出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra20729k
关键词
-
资金
- Natural Science Foundation of China [21402014, 21272077]
- Natural Science Foundation of Jiangsu Province [BK20131143]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PADA)
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
A copper(II) acetate catalyzed ring-opening cross-coupling of cyclopropanol with sulfonyl azide has been developed. By this method, various beta-amino ketones have been made efficiently in medium to high yields and venerable functional groups such as benzylic C-H, alkyl and aryl bromides, alkyl sulfonate, silyl ether and alkene are compatible with these reaction conditions. Control experiments have precluded the involvement of both radical and simple copper nitrene intermediates and a possible mechanism featuring key steps of ring-opening metalation and alkyl group migratory insertion into copper nitrene has been proposed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据