期刊
RSC ADVANCES
卷 5, 期 111, 页码 91683-91685出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra18555f
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资金
- Scientific Research Fund of Sichuan Provincial Education Department [13TD0022]
- Open Project of State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials [11zxfk26, 13zxfk06]
- Doctoral Research Foundation of Southwest University of Science and Technology [13zx7134]
A regioselective mono-alkenylation of o-carboranes on B(8) and B(9) via palladium catalyzed Heck type coupling of a cage B-H bond has been developed, and kinds of B(8)/B(9)-alkenyl-o-carboranes decorated with active groups have been synthesized withmoderate yield as well as good regioselectivity. A PdII catalyzed electrophilic B-H activation mechanism was also proposed.
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