4.6 Article

A novel Pd/C-catalyzed conversion of glucose to 1,2-propanediol by water splitting with Zn

期刊

RSC ADVANCES
卷 5, 期 63, 页码 51435-51439

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra08482b

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资金

  1. National Natural Science Foundation of China [21277091, 51472159]
  2. State Key Program of National Natural Science Foundation of China [21436007]
  3. Key Basic Research Projects of Science, Technology Commission of Shanghai [14JC1403100]
  4. China Postdoctoral Science Foundation [2013M541520]
  5. state key laboratory of coal-based low carbon energy, ENN

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A novel Pd/C-catalysed conversion of glucose to 1,2-propanediol by water splitting with Zn was proposed. The yield of 1,2-akanediols reached 48%, mainly including 1,2-propanediol (33.3%), the reported highest yield from glucose. Water, as a solvent, provides an in situ and active hydrogen source. The formed ZnO acts as a catalyst with Pd/C.

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