Synthesis, characterisation and application of imidazolium based ionic liquid modified montmorillonite sorbents for the removal of amaranth dye

The removal of amaranth dye using montmorillonite modified with an ionic liquid (IL) was investigated. An ionic liquid (1-methyl, 3-decahexyl imidazolium) was synthesised, and characterised by nuclear magnetic resonance (H-1 and C-13 NMR), Fourier transform infrared (FT-IR) spectroscopy, high resolution mass spectroscopy (HR-MS) as well as thermal gravimetric analysis and differential thermal (TGA/DCS) analysis. The ionic liquid was thereafter used to modify sodium montmorillonite (Na+-Mt) to form a hydrophobic montmorillonite that has a positively charged surface, by adding IL in excess of the cation exchange capacity (CEC) of Na+-Mt. Energy dispersive X-ray analyser (EDX) was used to determine the chemical composition of Na+-Mt. Modified montmorillonite (Mt-IL) and Na+-Mt was characterised using FT-IR, scanning electron microscopy (SEM), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) method, and used in the adsorption study of an anionic amaranth dye. A higher CEC of the Mt-IL (112 meq per 100 g) than Na+-Mt (89 meq per 100 g) was observed. The effects of sorbent dosage, dye concentration, solution pH and contact time were investigated in order to determine optimal experimental conditions. Optimum adsorption was obtained at pH 2 and adsorption data was better described by the pseudo-second-order kinetics and Langmuir adsorption isotherm. A maximum adsorption capacity of 263.2 mg g(-1) was calculated. The thermodynamic parameters Delta G degrees, Delta H degrees and Delta S degrees were also investigated at temperatures of 313, 303 and 293 K. Column studies were performed on the modified material and the data generated was applied to the Thomas model where high column adsorption capacities of 393.7, 580.9 and 603.6 mg g(-1) at different concentrations were obtained.