Inhibition of copper dissolution in water solutions of triazoles

The influence of the chemical structure of certain triazoles on the inhibition of copper dissolution in water solutions at pH 7.40 is studied by electrochemical and ellispometric means. It is established that adsorption of the studied triazoles on copper at potential E = 0.0 V relative to a normal hydrogen electrode is polymolecular, the first layer is described by the Frumkin equation with values of the free adsorption of energy values (-Delta G (a) (0) ) = 50.5-70.1 kJ/mol. In addition, possible orientations of triazole molecules with respect to a surface of oxidized copper are revealed.