4.2 Article

Polymer sorbent with the properties of an artificial cholesterol receptor

期刊

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 89, 期 2, 页码 288-290

出版社

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024415020211

关键词

molecularly imprinted sorbents; specific and nonspecific sorption; cholesterol; imprint sites

资金

  1. Russian Foundation for Basic Research [13-03-00445]

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A cholesterol-imprinted polymer sorbent and the corresponding reticular control copolymer were synthesized from hydroxyethyl methacrylate and ethyleneglycol dimethacrylate. The sorption isotherms of cholesterol were analyzed using the generalized Langmuir and Freundlich equations. In the case of the imprinted reticular polymer, cholesterol sorption occurred on the energetically homogeneous binding centers, forming one monolayer, while the nonspecific sorption of cholesterol on the control copolymer occurred with energetically nonhomogeneous binding of the sorbate and depended on the physicochemical conditions of sorption.

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