4.2 Article

The influence of water on the physicochemical characteristics of 1-butyl-3-methylimidazolium bromide ionic liquid

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RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 82, 期 7, 页码 1098-1103

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MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S003602440807008X

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A modified synthesis of 1-butyl-3-methylimidazolium bromide (BMImBr) was suggested and performed, and some physicochemical properties of the product containing 0.64-13.6 wt % water were determined. Water increased the electrical conductivity and decreased the viscosity and melting point of the substance but weakly influenced its density. Water in amounts of 5-8 wt % (45-50 mol %) caused structural changes. The BMImBr center dot 0.5H(2)O crystal hydrate was found to be stable thermodynamically.

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