期刊
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
卷 45, 期 9, 页码 1318-1324出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428009090036
关键词
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(+)-Disparlure [(7R,8S)-7,8-epoxy-2-methyloctadecane, pheromone of the gypsy moth Lymantria dispar L.] was synthesized starting from diethyl (-)-malate via cyclopropanation of the ester groups, selective protection of the 1,3-diol functionality, and successive opening and fragmentation of the three-membered rings in the corresponding tertiary cyclopropanols as key stages.
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