期刊
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷 59, 期 8, 页码 838-843出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023614080142
关键词
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Subsolidus phase ratios of the Na2MoO4-CoMoO4-Sc-2(MoO4)(3) system have been studied by X-ray diffraction, differential thermal analysis, and vibrational spectroscopy. A phase of variable composition Na1 - x Co1 - x Sc1 + x (MoO4)(3), 0 a parts per thousand currency sign x a parts per thousand currency sign 0.5 having NASICON structure (space group ) and triple molybdate NaCo3Sc(MoO4)(5) crystallizing in triclinic system (space group ) have been obtained. The high conductivity of Na1 - x Co1 - x Sc1 + x (MoO4)(3) allows the phase of variable composition to be regarded as a promising sodium-ion conducting solid electrolyte.
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