期刊
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷 56, 期 8, 页码 1189-1193出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023611080122
关键词
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Ag1-xMg1-xR1+x(MoO4)(3) NASICON-like solid solutions, where R = Al or Sc and 0 <= x <= 0.5, were prepared; their crystal lattice parameters and thermal stabilities were determined. Silver-ion conductivity was measured, and conductivity activation energy values were calculated for various temperature ranges. Above 400 degrees C, Ag1-xMg1-xR1+x(MoO4)(3) phases have ionic conductivities comparable to the conductivities of sodium-ion and lithium-ion NASICON-like conductors. The conductivity increases as the tervalent cation radius increases or the amount of mobile silver ions increases.
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