Organometallic polymers MF3(4,4'-Bipy) with M = Ga and In

Organometallic polymers MF3(4,4'-Bipy) with M = Ga and In are synthesized by the hydrothermal method. According to X-ray diffraction data, in a metal atom in the polymeric structure is octahedrally coordinated by four fluorine atoms and two nitrogen atoms. Bridging fluorine atoms and bidentate-bridging 4,4'-Bipy molecules join the complexes into layers.