期刊
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
卷 84, 期 11, 页码 2228-2233出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363214110310
关键词
bond energy; enthalpy of reaction; adiabatic temperature rise; non-isothermal reactor
资金
- European Regional Development Fund under CEBIA-Tech [CZ.1.05/2.1.00/03.0089]
- Tomas Bata University [IGA/FAI/2014/011]
- National Council of Science and Technology (CONACYT) in Mexico
The paper presents determination of adiabatic temperature rise during the oxidation of glycerol to glyceraldehyde with hydrogen peroxide in order for estimating its potential hazardous behavior. Estimation of enthalpy of the reaction was carried out by using thermodynamic tables and the bond energy method. The Nonisothermal reaction system for glycerol oxidation was described on the basis of a dynamic modeling proposal, considering the energy balance in the reactor to describe the final stage in the process of glycerol oxidation. The objectives of the present study were determination of the physic-mathematical model for glycerol oxidation, performance of the linearization of the proposed model and determination of transfer function for control purposes.
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