期刊
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
卷 79, 期 12, 页码 2723-2730出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363209120317
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资金
- Russian Foundation for Basic Researh [06-03-32096]
- Analytical Departmental Target program
Basic structural principles of uranyl selenates with organic templates are outlined as follows. In compounds with short chain amine molecules (C:N < 8) the primary role plays the correspondence between topology of inorganic complex (isomerism) and structure and shape of a template. In the structures with long chain molecules (C:N a parts per thousand currency sign 8), the molecules are associated to form 2- or 1-dimensional supramolecular templates that are connected with inorganic structure according to the charge density matching principle. Compounds with electro neutral molecules (crown ethers) have composite structure, where bonding between organic and inorganic parts is achieved through hydrogen bonding via intermediate oxonium clusters.
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