期刊
RSC ADVANCES
卷 5, 期 62, 页码 50580-50590出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra06429e
关键词
-
资金
- CSIR, New Delhi, India [CSC-0108, CSC-0301]
Concise total syntheses of (R)-pipecolic acid, (R)-ethyl-6-oxopipecolate, (2R, 3R)-3-hydroxypipecolic acid and formal syntheses of beta-(+)-conhydrine, (-)-lentiginosine, (-)-swainsonine and 1,2-di-epi-swainsonine have been accomplished starting from a common chiral synthon. The present strategy employs regioselective aziridine ring opening, Wittig olefination and RCM as the key chemical transformations.
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