期刊
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
卷 38, 期 5, 页码 353-362出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070328412050065
关键词
-
资金
- Federal Target Program Scientific and Pedagogical Personnel of an Innovative Russia [02.740.11.0628]
New complexes of Co(II), Ni(II), and Cu(II) nitrates, chlorides, and perchlorates with 4-(4-hydroxyphenyl)-1,2,4-triazole (L) were obtained and examined by single-crystal X-ray diffraction, X-ray powder diffraction, and electronic absorption and IR spectroscopy. The cations of all the complexes have linear trinuclear structures. Ligand L is coordinated to the metal ions in a bidentate bridging fashion through the N(1) and N(2) atoms of the heterocycle. The coordination polyhedron of the metal atoms is a distorted octahedron. The molecular and crystal structures of the complexes [Co3L6(H2O)(6)](ClO4)(6) center dot 3C(2)H(5)OH center dot 3.75H(2)O and [M3L6(H2O)(6)](ClO4)(6) center dot 6H(2)O (M = Cu2+ and Ni2+) were determined.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据