期刊
RSC ADVANCES
卷 5, 期 75, 页码 60914-60919出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra10246d
关键词
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资金
- Institute for Basic Science [IBSR-011-D1]
- ISTK [CAP-13-2-ETRI]
In order to obtain a high performance supercapacitor, there are several factors that must be achieved including a high specific surface area (SSA), high electrical conductivity, and a high diffusion rate of the electrolyte due to an appropriate pore volume. Herein, we report a high performance supercapacitor using activated non-stacked reduced graphene oxide (a-NSrGO) that has a high SSA (up to 999.75 m(2) g(-1)) with intrinsic high graphene conductivity (1202 S m(-1)) and fast diffusion of the electrolyte. Due to a high total pore volume (5.03 cm(3) g(-1)) and a wide pore size distribution from macro-to micropores (main pore width: 0.61 - 0.71 nm) in the a-NSrGO sheets, the as-prepared a-NSrGO electrode shows high specific capacitance (105.26 F g(-1)) and a short relaxation time (tau(0) = 1.5 s) in a propylene carbonate (PC)-based organic electrolyte. A maximum energy density of 91.13 W h kg(-1) and a power density of 66 684.73 W kg(-1) were estimated in a fully packaged coin cell. The high performance of the a-NSrGO supercapacitors is attributed to their specific appearance and enlarged pore distribution with high SSA.
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