期刊
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
卷 86, 期 7, 页码 1064-1069出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S1070427213070197
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资金
- Ministry of Education and Science of the Russian Federation
Acid dissociation constants for three main types of phenol structural fragments of lignin in binary mixtures of water with N,N-dymethylformamide, dimethyl sulfoxide, and 1,4-dioxane were determined by spectrophotometric potentiometric titration. The effect of solvent on lignin protolytic properties was examined on the basis of the Kamlet-Taft principle of linear relationship of free solvation energies. It was found that nonspecific interactions with solvent make the dominating contribution to the effect of the medium.
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