期刊
RSC ADVANCES
卷 5, 期 125, 页码 103350-103357出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra21838a
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资金
- UGC
- CSIR, New Delhi
A rhodamine-pyridine conjugate, REDA-2PC, can selectively detect NCS- in human embryonic kidney 293 (HEK293) cells. DFT calculations suggest that this is due to non-covalent interactions (hydrogen bonding N-H center dot center dot center dot NCS-, pi-pi stacking) and long range electrostatic forces acting between the sulfur atom of the NCS- anion and the NEt2 unit of REDA-2PC. A visible light excitable probe allows fluorescence and naked eye detection of nanomolar NCS-, much lower than normal NCS- levels in the human body. A lock and key sensing mechanism is established and compared with the corresponding fluorescein derivative as a model compound.
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