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Direct nucleophilic functionalization of C(sp2)-H-bonds in arenes and hetarenes by electrochemical methods

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RUSSIAN CHEMICAL REVIEWS
卷 82, 期 8, 页码 747-771

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TURPION LTD
DOI: 10.1070/RC2013v082n08ABEH004386

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The data on the main electrochemical methods and approaches used for the direct functionalization of the C(sp(2)) - H-bond proceeding via the mechanisms of nucleophilic substitution of hydrogen (S-N(H)-reaction) are classified and summarized. The important features of preparative electrochemical processes are considered. A special emphasis is placed on the synthetic potential of the discussed transformations. The bibliography includes 133 references.

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