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Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds

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RUSSIAN CHEMICAL REVIEWS
卷 78, 期 4, 页码 319-328

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TURPION LTD
DOI: 10.1070/RC2009v078n04ABEH003904

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  1. Division of Chemistry and Materials Science of the RAS
  2. RF Ministry of Education and Science [NSh-5236-2006.3]

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Mercury isotope effects in environmentally significant chemical and biochemical reactions are considered. The recently discovered anomaly for the Hg-199 and Hg-201 magnetic nuclei proves that both chemical and biochemical transformations of mercury compounds (outside and inside living organisms) follow radical spin-selective mechanisms. The regularities of isotope fractionation in natural photochemical processes and in living tissues are discussed. The bibliography includes 22 references

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