期刊
RUSSIAN CHEMICAL REVIEWS
卷 78, 期 6, 页码 535-568出版社
TURPION LTD
DOI: 10.1070/RC2009v078n06ABEH004026
关键词
-
资金
- Russian Foundation for Basic Research [08-03-00100]
The literature data on the controlled synthesis of macromolecules using nitroxide radicals formed in situ in the course of polymerization as the regulators of polymer chain propagation are systematized and generalized. Attention is focused on the mechanism of control over the polymer chain propagation in the radical homopolymerization under conditions of the reversible inhibition and on the effect of the structure of precursors and regulating additives on the polymerization kinetics of different monomers and the molecular-weight characteristics of the synthesized high molecular-weight compounds. The main methods for the in situ generation of stable nitroxide radicals are considered. The prospects for the development and practical application of the mentioned approaches to the synthesis of new polymeric materials are assessed. The bibliography includes 238 references.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据