4.5 Review

Organocatalysis of asymmetric aldol reaction. Catalysts and reagents

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RUSSIAN CHEMICAL REVIEWS
卷 78, 期 8, 页码 737-784

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TURPION LTD
DOI: 10.1070/RC2009v078n08ABEH004040

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  1. Russian Foundation for Basic Research [09-03-12164-ofi-m, 09-03-00384-a, 08-03-00659-a, 08-03-92505-NTsNIL-a, 08-03-91308-IND-a]

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The review is devoted to the application of organocatalysis for the asymmetric aldol reaction, which is one of the most important methods for carbon-carbon bond formation in organic compounds. The mechanism of enamine catalysis and the main types of organocatalysts for the aldol reaction are considered, data on this type of reactions involving carbonyl compounds with various electronic and spatial structures are classified. The effects of organocatalyst structure on the regio-, stereo- and enantio-selectivity of intramolecular and intermolecular aldol react ions are reviewed. The bibliography includes 355 references.

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