期刊
RUSSIAN CHEMICAL BULLETIN
卷 58, 期 6, 页码 1119-1125出版社
SPRINGER
DOI: 10.1007/s11172-009-0145-9
关键词
urea; creatinine; organic nickel(II) complexes; chronoamperometry; voltammetry; electrocatalysis
资金
- Russian Foundation for Basic Research [06-03-08141-ofi, 07-03-96068-r_ural_a, 07-03-96112-r_ural_a, 07-03-96113-r_ural_a]
The organic nickel(ii) complexes with catalytic activity in the electrochemical oxidation of creatinine and urea were synthesized and studied. The signals of electrocatalytic oxidation of the studied carbonyl-containing amines in model solutions were obtained. The detection limit (by the 3 sigma-criterion) is 8.7 center dot 10(-6) and 2.7 center dot 10(-5) mol L-1 for urea and creatinine, respectively.
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