期刊
RENEWABLE ENERGY
卷 38, 期 1, 页码 163-168出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2011.07.017
关键词
Dye-sensitized solar cells; Squaraine dye; TiO(2)
资金
- National Natural Science foundation of China [20575042]
- Education Ministry of China [105141]
- Sichuan Science & Technology Supported Project of Sichuan Province, China [2008GZ0041, 2009GZ0167]
An unsymmetrical squaraine dye which contains an arylamino group was synthesized and used in dye-sensitized solar cells. The molar extinction coefficient of the dye is 77793 M(-1) cm(-1). Because our synthesized molecule may have no diradical character or the contribution of the diradicaloid component to resonance is quite small, the newly designed squaraine dye has a maximum absorption at 546 nm in the visible region compared with the NIR squaraine sensitizers. Cyclic voltammetry and time dependent density function theory calculation were accomplished to scrutinize the sensitized performance of the dye. Meanwhile, the novel sensitizer has been used to sensitize nanocrystalline TiO(2)-based solar cell. Under standard global AM 1.5 solar conditions, the squaraine dye-sensitized cell gives a short circuit photocurrent density (J(SC)) of 5.84 mA/cm(2), an open circuit voltage of (V(OC)) 0.658 V, and a fill factor (if) of 0.448, corresponding to an overall conversion efficiency (eta) of 1.72%. (C) 2011 Elsevier Ltd. All rights reserved.
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