期刊
REACTIVE & FUNCTIONAL POLYMERS
卷 71, 期 9, 页码 948-957出版社
ELSEVIER
DOI: 10.1016/j.reactfunctpolym.2011.06.004
关键词
Acrylic polymers; Polymethacrylates; Crown ethers; Podands
资金
- Spanish Ministerio de Ciencia e Innovacion - Feder [MAT2008-00946]
- Junta de Castilla y Leon [BU001A10-2]
The synthesis and radical polymerisation of methacrylic monomers with benzo-12-crown-4, benzo-15-crown-5, benzo-18-crown-6, and their dipodal counterparts in the ester residue is described. The radical polymerisation of the monomers in solution was carried out at different temperatures, and the polymerisation kinetics curves were obtained by direct measurement of the instantaneous monomer concentrations by nuclear magnetic resonance spectroscopy (NMR). Thus, the polymerisation rate parameter (2fk(p)/(k(t))(1/2)), along with the polymer stereoregularity, were obtained in terms of the molar fractions of meso and racemo diads and of syndiotactic, isotactic and heterotactic triads. The interaction of the polymers with cations was studied using polymer networks as solid phases in the solid-liquid extraction of lanthanide cations from both organic and aqueous media. (C) 2011 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据