期刊
REACTIVE & FUNCTIONAL POLYMERS
卷 71, 期 6, 页码 625-633出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.reactfunctpolym.2011.03.001
关键词
Methacrylate monomers; Suspension polymerization; Microspheres; Porous polymers; Textural properties; Thermal analysis; Chromatographic retention selectivity of polymers
Permanently porous copolymers derived from multifunctional methacrylate monomers were prepared by suspension polymerization. The polymerization process was carried out in the presence of toluene and decan-1-ol used as pore forming diluents. Influence of chemical structure of monomers on porous structure of the studied microspheres, the residual C=C bonds, and their thermal properties was studied. Moreover, chromatographic retention selectivity of methacrylate microspheres was determined and compared with the commercially available polymeric stationary phase - Porapak Q. (C) 2011 Elsevier Ltd. All rights reserved.
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