期刊
REACTIVE & FUNCTIONAL POLYMERS
卷 69, 期 9, 页码 650-654出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.reactfunctpolym.2009.04.006
关键词
Biomimetic catalyst; Heterogeneous catalysts; Molecular imprinting; Asymmetric hydrogenation; Bis(oxazoline); Enamides
资金
- National Institutes of Health (NIH) [3506GM053933]
A new class of heterogeneous catalysts for asymmetric hydrogenation of enamides was synthesized using molecular imprinting technology. These new catalysts are molecularly imprinted polymers (MIPs) made from rhodium (I) and copper (II) complexes with the bis(oxazoline) chiral ligands. One of the Rh-MIPs showed 87% ee toward L-enantiomeric product while the Cu-MIP showed 82% ee toward D-enantiomeric product. Both MIPs are easy to separate and reusable. (C) 2009 Elsevier Ltd. All rights reserved.
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