LiNi0.7Co0.15Mn0.15O2 microspheres as high-performance cathode materials for lithium-ion batteries

Advanced uniform LiNi0.7Co0.15Mn0.15O2 microspheres were successfully synthesized and examined as cathode materials for lithium-ion batteries. The structure, morphology, and electrochemical performance of LiNi0.7Co0.15Mn0.15O2 calcined at different temperatures ranging from 650 to 900 A degrees C were systematically investigated. The XRD results show that the material has a well-ordered layered structure with small amount of cation mixing. A distinct spherical morphology of the obtained powders prepared at different temperatures can be seen from the SEM images. The as-synthesized LiNi0.7Co0.15Mn0.15O2 powders have a very high-tap density of about 2.37 g center dot cm(-3). Among all the samples, the sample calcined at 750 A degrees C exhibits the best electrochemical performance with an initial discharge capacity of 185.2 mAh center dot g(-1) (3.0-4.3 V, 0.2C rate) and capacity retention > 94.77 % after 50 cycles. Moreover, this material shows high-specific capacity and good cycling stability. The LiNi0.7Co0.15Mn0.15O2 microspheres with high-specific capacity and high-tap density are promising to use as cathode materials for next-generation high-energy-density lithium-ion batteries.