期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 5, 期 4, 页码 2467-2477出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy01622j
关键词
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资金
- UNIK research initiative Catalysis for Sustainable Energy and Lundbeck [R45-A3878]
The oxidative dehydrogenation of alcohols to carbonyl compounds was studied using CuO nanoparticle catalysts prepared by solution synthesis in buffered media. CuO nanoparticles synthesized in N-cyclohexyl-3- aminopropanesulfonic acid buffer showed high catalytic activity for the oxidation of benzylic, alicyclic and unsaturated alcohols to their corresponding carbonyl compounds with excellent selectivities. The observed trend in activity for conversion of substituted alcohols suggested a beta-H elimination step to be involved, thus enabling a possible reaction mechanism for oxidative dehydrogenation of benzyl alcohols to be proposed. The use of CuO as an inexpensive and efficient heterogeneous catalyst under aerobic conditions provides a new noble metal-free and green reaction protocol for carbonyl compound synthesis.
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