期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 5, 期 3, 页码 1919-1928出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy01517g
关键词
-
资金
- European Research Council (ERC) [338846]
- Dutch National Research School Combination Catalysis (NRSCC)
Palladium nanoparticles of similar size of similar to 2 nm were synthesized on different silica-based materials, all functionalized with thiol groups i.e., Aerosil-380, SBA-15, plugged SBA-15 and m-MCF. The resulting materials were used to study the influence of the confinement of Pd nanoparticles in a functionalized silica support on the Heck and the Suzuki reactions. In the case of the Heck reaction, for all catalysts it was proven that leached Pd species were responsible for the activity. However, the catalysts based on ordered mesoporous silica were still able to restrict Pd particle growth, giving rise to an enhanced stability. For the Suzuki reaction, stronger alkaline conditions were required and catalysts based on plugged SBA-15 showed a higher stability than those based on SBA-15 and m-MCF, which both collapsed after the first cycle. At almost identical Pd particle size, ordered mesoporous materials enhance stability and particle growth is slowed down but not fully suppressed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据